Change of Spectral Photoluminescent Properties of Milk during Souring

Introduction. The use of digital technologies will increase the efficiency of animal husbandry. These technologies include optical monitoring of product quality. The aim of the research is to study the dependence of the spectral characteristics and parameters of excitation and luminescence of milk d...

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Main Authors: Mikhail V. Belyakov, Gennady N. Samarin, Alexander A. Kudryavtsev, Igor Yu. Efremenkov
Format: Article
Language:English
Published: National Research Mordova State University; MRSU 2022-09-01
Series:Инженерные технологии и системы
Subjects:
Online Access:https://vestnik.mrsu.ru/index.php/en/articles2-en/111-22-3/1018-10-15507-0236-2910-032-202203-8
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author Mikhail V. Belyakov
Gennady N. Samarin
Alexander A. Kudryavtsev
Igor Yu. Efremenkov
author_facet Mikhail V. Belyakov
Gennady N. Samarin
Alexander A. Kudryavtsev
Igor Yu. Efremenkov
author_sort Mikhail V. Belyakov
collection DOAJ
description Introduction. The use of digital technologies will increase the efficiency of animal husbandry. These technologies include optical monitoring of product quality. The aim of the research is to study the dependence of the spectral characteristics and parameters of excitation and luminescence of milk during souring. Materials and Methods. The milk with a fat content of 3.2% was used for measurements. The acidity was controlled by the titrimetric method. The excitation and luminescence registration spectra were measured on a Fluorat-02-Panorama spectrofluorimeter in the range of 200–500 nm. Spectra parameters were calculated in the PanoramaPro and Microcal Origin programs. Results. When milk sours, excitation spectra shift downwards, while a qualitative change in characteristics is observed with the range of 350–500 nm, although the photoelectric signal absolute level is almost an order of magnitude less than with a range of 220?340 nm. The photoluminescence flux when excited by the radiation with wavelength of 262 nm decreases during the souring process. The flux excited by the radiation with wavelength of 385 nm increases especially in the first three days. The flux at wavelength of 442 nm decreases slightly. Statistical parameters and energy of photoluminescence spectra are not informative for the milk souring control. The dependence of the ratio of photoluminescence fluxes excited by the radiation of 385 and 442 nm on acidity is linearly approximated with a determination coefficient of 0.99. Discussion and Conclusion. The change in the milk luminescent properties can be used as a marker of its souring with acidity control. To create a method for monitoring milk quality indicators during souring, the most informative is the use of excitation wavelengths of 385 and 442 nm with subsequent registration of photoluminescence in the ranges 440–490 and 490–600 nm respectively.
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spelling doaj.art-7a8985870b8f4991addbc12b17dcda7f2022-12-22T04:29:16ZengNational Research Mordova State University; MRSUИнженерные технологии и системы2658-41232658-65252022-09-0132346047510.15507/2658-4123.032.202203.460-475Change of Spectral Photoluminescent Properties of Milk during SouringMikhail V. Belyakov0https://orcid.org/0000-0002-4371-8042Gennady N. Samarin1https://orcid.org/0000-0002-4972-8647Alexander A. Kudryavtsev2https://orcid.org/0000-0002-6122-0168Igor Yu. Efremenkov3https://orcid.org/0000-0003-2302-9773Federal Scientific Agroengineering Center VIM Federal Scientific Agroengineering Center VIM Federal Scientific Agroengineering Center VIM Moscow Power Engineering InstituteIntroduction. The use of digital technologies will increase the efficiency of animal husbandry. These technologies include optical monitoring of product quality. The aim of the research is to study the dependence of the spectral characteristics and parameters of excitation and luminescence of milk during souring. Materials and Methods. The milk with a fat content of 3.2% was used for measurements. The acidity was controlled by the titrimetric method. The excitation and luminescence registration spectra were measured on a Fluorat-02-Panorama spectrofluorimeter in the range of 200–500 nm. Spectra parameters were calculated in the PanoramaPro and Microcal Origin programs. Results. When milk sours, excitation spectra shift downwards, while a qualitative change in characteristics is observed with the range of 350–500 nm, although the photoelectric signal absolute level is almost an order of magnitude less than with a range of 220?340 nm. The photoluminescence flux when excited by the radiation with wavelength of 262 nm decreases during the souring process. The flux excited by the radiation with wavelength of 385 nm increases especially in the first three days. The flux at wavelength of 442 nm decreases slightly. Statistical parameters and energy of photoluminescence spectra are not informative for the milk souring control. The dependence of the ratio of photoluminescence fluxes excited by the radiation of 385 and 442 nm on acidity is linearly approximated with a determination coefficient of 0.99. Discussion and Conclusion. The change in the milk luminescent properties can be used as a marker of its souring with acidity control. To create a method for monitoring milk quality indicators during souring, the most informative is the use of excitation wavelengths of 385 and 442 nm with subsequent registration of photoluminescence in the ranges 440–490 and 490–600 nm respectively.https://vestnik.mrsu.ru/index.php/en/articles2-en/111-22-3/1018-10-15507-0236-2910-032-202203-8milkacidityoptical spectraphotoluminescence fluxlinear regression model
spellingShingle Mikhail V. Belyakov
Gennady N. Samarin
Alexander A. Kudryavtsev
Igor Yu. Efremenkov
Change of Spectral Photoluminescent Properties of Milk during Souring
Инженерные технологии и системы
milk
acidity
optical spectra
photoluminescence flux
linear regression model
title Change of Spectral Photoluminescent Properties of Milk during Souring
title_full Change of Spectral Photoluminescent Properties of Milk during Souring
title_fullStr Change of Spectral Photoluminescent Properties of Milk during Souring
title_full_unstemmed Change of Spectral Photoluminescent Properties of Milk during Souring
title_short Change of Spectral Photoluminescent Properties of Milk during Souring
title_sort change of spectral photoluminescent properties of milk during souring
topic milk
acidity
optical spectra
photoluminescence flux
linear regression model
url https://vestnik.mrsu.ru/index.php/en/articles2-en/111-22-3/1018-10-15507-0236-2910-032-202203-8
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