Hybrid Silsesquioxane/Benzoate Cu<sub>7</sub>-Complexes: Synthesis, Unique Cage Structure, and Catalytic Activity

Hybrid Silsesquioxane/Benzoate Cu<sub>7</sub>-Complexes: Synthesis, Unique Cage Structure, and Catalytic Activity

A series of phenylsilsesquioxane-benzoate heptacopper complexes <b>1</b>–<b>3</b> were synthesized and characterized by X-ray crystallography. Two parallel routes of toluene spontaneous oxidation (into benzyl alcohol and benzoate) assisted the formation of the cagelike struct...

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Bibliographic Details
Main Authors: Alexey N. Bilyachenko, Victor N. Khrustalev, Evgenii I. Gutsul, Anna Y. Zueva, Alexander A. Korlyukov, Lidia S. Shul’pina, Nikolay S. Ikonnikov, Pavel V. Dorovatovskii, Dmitri Gelman, Elena S. Shubina, Georgiy B. Shul’pin
Format: Article
Language:English
Published: MDPI AG 2022-12-01
Series:Molecules
Subjects:
metallasilsesquioxanes
cagelike compounds
benzoate ligands
oxidative catalysis
alkanes
alkyl hydroperoxide
Online Access:https://www.mdpi.com/1420-3049/27/23/8505

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https://www.mdpi.com/1420-3049/27/23/8505

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