A hierarchically assembled 88-nuclei silver-thiacalix[4]arene nanocluster
The assembly of giant silver clusters by using macrocylic multidentate ligand remains a challenge. Here, the authors synthesize a chromate-templated 88-nuclei silver super calix and reveal the role of anion templating effects and a hierarchical assembly mechanism.
| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2020-01-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-019-13682-5 |