Conductive Self-Assembled Monolayers of Paramagnetic {CoIICo4III} and {Co4IICo2III} Coordination Clusters on Gold Surfaces

Conductive Self-Assembled Monolayers of Paramagnetic {CoIICo4III} and {Co4IICo2III} Coordination Clusters on Gold Surfaces

Two polynuclear cobalt(II,III) complexes, [Co5(N3)4(N-n-bda)4(bza·SMe)2] (1) and [Co6(N3)4(N-n-bda)2(bza·SMe)5(MeOH)4]Cl (2), where Hbza·SMe = 4-(methylthio)benzoic acid and N-n-H2bda = N-n-butyldiethanolamine, were synthesized and fully characterized by various techniques. Compound 1 exhibits an un...

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Bibliographic Details
Main Authors: Sebastian Schmitz, Xinkai Qiu, Maria Glöß, Jan van Leusen, Natalya V. Izarova, Muhammad Arif Nadeem, Jan Griebel, Ryan C. Chiechi, Paul Kögerler, Kirill Yu. Monakhov
Format: Article
Language:English
Published: Frontiers Media S.A. 2019-11-01
Series:Frontiers in Chemistry
Subjects:
cobalt
magnetochemistry
gold surface
molecular conductivity
eutectic gallium–indium electrode
Online Access:https://www.frontiersin.org/article/10.3389/fchem.2019.00681/full

Internet

https://www.frontiersin.org/article/10.3389/fchem.2019.00681/full

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