Synthesis, Crystal Structures and Magnetic Properties of Composites Incorporating an Fe(II) Spin Crossover Complex and Polyoxometalates

Synthesis, Crystal Structures and Magnetic Properties of Composites Incorporating an Fe(II) Spin Crossover Complex and Polyoxometalates

[Fe(dppOH)2]2+ (dppOH = 2,6-di(pyrazol-1-yl)-4-(hydroxymethyl)pyridine) is known to show spin crossover (SCO) behavior and light-induced excited spin state transitions (LIESST). Here, we show that the SCO properties of the [Fe(dppOH)2]2+ complex can be altered by a crystal engineering approach emplo...

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Bibliographic Details
Main Authors: Satoshi Kuramochi, Takuya Shiga, Jamie M. Cameron, Graham N. Newton, Hiroki Oshio
Format: Article
Language:English
Published: MDPI AG 2017-07-01
Series:Inorganics
Subjects:
spin crossover
polyoxometalate
crystal engineering
magnetic properties
iron
Online Access:https://www.mdpi.com/2304-6740/5/3/48

Internet

https://www.mdpi.com/2304-6740/5/3/48

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