Synthesis of Macrocyclic Ketones by Repeatable Two-Carbon Ring Expansion Reactions
A novel and short method for the synthesis of macrocyclic alkanones has been developed: medium- and large-ring 1-vinylcycloalkanols can be transformed directly and efficiently into the isomeric, ring-expanded bishomologous macrocyclic ketones by a thermal 1,3-C shift rearrangement reaction...
| Main Authors: | , , |
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| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
2003-04-01
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| Series: | CHIMIA |
| Subjects: | |
| Online Access: | https://www.chimia.ch/chimia/article/view/3689 |