On the Coexistence of the Carbene⋯H-D Hydrogen Bond and Other Accompanying Interactions in Forty Dimers of N-Heterocyclic-Carbenes (I, IMe<sub>2</sub>, I<sup><i>i</i></sup>Pr<sub>2</sub>, I<sup><i>t</i></sup>Bu<sub>2</sub>, IMes<sub>2</sub>, IDipp<sub>2</sub>, IAd<sub>2</sub>; I = imidazol-2-ylidene) and Some Fundamental Proton Donors (HF, HCN, H<sub>2</sub>O, MeOH, NH<sub>3</sub>)

On the Coexistence of the Carbene⋯H-D Hydrogen Bond and Other Accompanying Interactions in Forty Dimers of N-Heterocyclic-Carbenes (I, IMe<sub>2</sub>, I<sup><i>i</i></sup>Pr<sub>2</sub>, I<sup><i>t</i></sup>Bu<sub>2</sub>, IMes<sub>2</sub>, IDipp<sub>2</sub>, IAd<sub>2</sub>; I = imidazol-2-ylidene) and Some Fundamental Proton Donors (HF, HCN, H<sub>2</sub>O, MeOH, NH<sub>3</sub>)

The subject of research is forty dimers formed by imidazol-2-ylidene (I) or its derivative (IR<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>2</mn></msub><...

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Bibliographic Details
Main Author: Mirosław Jabłoński
Format: Article
Language:English
Published: MDPI AG 2022-09-01
Series:Molecules
Subjects:
carbene
N-heterocyclic carbene
NHC
imidazol-2-ylidene
hydrogen bond
intermolecular interaction
Online Access:https://www.mdpi.com/1420-3049/27/17/5712

Internet

https://www.mdpi.com/1420-3049/27/17/5712

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