Ligand-dependent stereoselective Suzuki–Miyaura cross-coupling reactions of β-enamido triflates

The stereoselective Suzuki–Miyaura cross-coupling of (Z)-β-enamido triflates is demonstrated. Depending on the nature of the ligand in the palladium catalyst, either retention or inversion of the configuration during the synthesis of β,β-diaryl-substituted enamides is observed. Thus, the method prov...

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Bibliographic Details
Main Authors: Tomáš Chvojka, Athanasios Markos, Svatava Voltrová, Radek Pohl, Petr Beier
Format: Article
Language:English
Published: Beilstein-Institut 2021-10-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.17.179