Thiol-ene click chemistry incorporates carboxylic acid-terminated alkane pendants on polycyclooctene to tune properties

Thiol-ene click chemistry incorporates carboxylic acid-terminated alkane pendants on polycyclooctene to tune properties

Dehydrogenation and subsequent chemical modification of polyolefins emerges as a promising polymer-to-polymer upcycling pathway. We report the functionalization of polycyclooctene (PCOE), a model for dehydrogenated polyethylene, by thiol-ene click chemistry to install carboxylic acid (COOH) terminat...

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Bibliographic Details
Main Authors: Eli Fastow, Roshni John Chethalen, E. Bryan Coughlin, Karen I. Winey
Format: Article
Language:English
Published: Elsevier 2024-03-01
Series:Giant
Subjects:
Polymer upcycling
Thiol-ene click chemistry
Polycyclooctene
Associating polymer
Functionalization
Dynamic mechanical analysis
Online Access:http://www.sciencedirect.com/science/article/pii/S2666542523000930

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http://www.sciencedirect.com/science/article/pii/S2666542523000930

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