Thiol-ene click chemistry incorporates carboxylic acid-terminated alkane pendants on polycyclooctene to tune properties

Thiol-ene click chemistry incorporates carboxylic acid-terminated alkane pendants on polycyclooctene to tune properties

Dehydrogenation and subsequent chemical modification of polyolefins emerges as a promising polymer-to-polymer upcycling pathway. We report the functionalization of polycyclooctene (PCOE), a model for dehydrogenated polyethylene, by thiol-ene click chemistry to install carboxylic acid (COOH) terminat...

Full description

Bibliographic Details
Main Authors:	Eli Fastow, Roshni John Chethalen, E. Bryan Coughlin, Karen I. Winey
Format:	Article
Language:	English
Published:	Elsevier 2024-03-01
Series:	Giant
Subjects:	Polymer upcycling Thiol-ene click chemistry Polycyclooctene Associating polymer Functionalization Dynamic mechanical analysis
Online Access:	http://www.sciencedirect.com/science/article/pii/S2666542523000930

Similar Items

Wood−Derived Polymers from Olefin−Functionalized Lignin and Ethyl Cellulose via Thiol–Ene Click Chemistry
by: Rongrong An, et al.
Published: (2023-04-01)

The Use of the Thiol-Ene Addition Click Reaction in the Chemistry of Organosilicon Compounds: An Alternative or a Supplement to the Classical Hydrosilylation?
by: Ilya Krizhanovskiy, et al.
Published: (2022-07-01)

Highly Water Dispersible Functionalized Graphene by Thermal Thiol-Ene Click Chemistry
by: Farzaneh Farivar, et al.
Published: (2021-05-01)

Photoinduced thiol-ene “click” chemistry for resource-efficient curing of polysilazane-based coatings and its effects on coating property profile
by: Michael Hoffmann, et al.
Published: (2023-09-01)

An excellent ozone-resistant polymethylvinylsiloxane coating on natural rubber by thiol-ene click chemistry
by: N. Y. Ning, et al.
Published: (2015-06-01)

Thiol-Ene Click-Inspired Late-Stage Modification of Long-Chain Polyurethane Dendrimers
by: Dhruba P. Poudel, et al.
Published: (2021-12-01)

Influence of Monomer Structure, Initiation, and Porosity on Mechanical and Morphological Characteristics of Thiol‐ene PolyHIPEs
by: Stanko Kramer, et al.
Published: (2023-08-01)

Functional Conducting Polymers via Thiol-ene Chemistry
by: David C. Martin, et al.
Published: (2012-08-01)

Chemical modification of Bombyx mori silk fibers with vinyl groups for thiol-ene click chemistry
by: Xiaoning Zhang, et al.
Published: (2019-09-01)

"Preparation of 1,2-polybutadiene coated silica using thiol-ene click method and its reinforcement for styrene-butadiene rubber"
by: JIAO Sheng-cheng
Published: (2024-01-01)

Thiol-ene Click Chemistry Using Triethylamine Gas as a Promoter to Make Coated Slow-release Fertilizer
by: Pengfei Shan, et al.
Published: (2021-11-01)

High wear-resisting,superhydrophobic coating with well aging resistance and ultrahigh corrosion resistant on high vinyl polybutadiene rubber substrate by thiol-ene click chemistry
by: Yudong Liu, et al.
Published: (2021-09-01)

Amphiphilic Bowl-Shaped Janus Particles Prepared via Thiol–Ene Click Reaction for Effective Oil–Water Separation
by: Xian Qi, et al.
Published: (2023-01-01)

Bio-Based Crosslinked Polymers Synthesized from Functionalized Soybean Oil and Squalene by Thiol–Ene UV Curing
by: Sigita Grauzeliene, et al.
Published: (2021-05-01)

A Highly Effective, UV-Curable, Intumescent, Flame-Retardant Coating Containing Phosphorus, Nitrogen, and Sulfur, Based on Thiol-Ene Click Reaction
by: Wenqian Li, et al.
Published: (2022-05-01)

Two-stage thiol-ene click reaction for fluorine-free superhydrophobic fabrics with buoyancy boost and drag reduction
by: Yudong Liu, et al.
Published: (2023-12-01)

Effect of Photoinitiator on Precursory Stability and Curing Depth of Thiol-Ene Clickable Gelatin
by: Kai-Hung Yang, et al.
Published: (2021-06-01)

Vegetable Oil-Based Thiol-Ene/Thiol-Epoxy Resins for Laser Direct Writing 3D Micro-/Nano-Lithography
by: Sigita Grauzeliene, et al.
Published: (2021-03-01)

Thiol‐ene Reaction as Reversible Covalent Bond for the Design of Shape‐Memory Polymers
by: Farhad Shohraty, et al.
Published: (2023-08-01)

Ionogels Obtained by Thiol-Ene Photopolymerization—Physicochemical Characterization and Application in Electrochemical Capacitors
by: Agnieszka Marcinkowska, et al.
Published: (2021-02-01)

The Influence of Monomer Structure on the Properties of Ionogels Obtained by Thiol–Ene Photopolymerization
by: Aneta Lewandowska, et al.
Published: (2021-11-01)

Recent Advances in Click Chemistry Applied to Dendrimer Synthesis
by: Mathieu Arseneault, et al.
Published: (2015-05-01)

Joint-Linker Type Ionic Gels Using Polymerizable Ionic Liquid as a Crosslinker via Thiol-Ene Click Reactions
by: Kumkum Ahmed, et al.
Published: (2020-11-01)

Thiol-Functional Polymer Nanoparticles via Aerosol Photopolymerization
by: Narmin Suvarli, et al.
Published: (2021-12-01)

Thiol-Ene Coupling of High Oleic Sunflower Oil towards Application in the Modification of Flexible Polyurethane Foams
by: Sylwia Dworakowska, et al.
Published: (2022-01-01)

RAFT-Based Polymers for Click Reactions
by: Elena V. Chernikova, et al.
Published: (2022-01-01)

Biobased dual-cure thiol-ene benzoxazine resins for high-performance polymer dielectrics
by: Yong Lu, et al.
Published: (2022-12-01)

Mechanical and Shape Memory Properties of Electrospun Polyurethane with Thiol-Ene Crosslinking
by: Sam Briggs, et al.
Published: (2022-01-01)

Modification of Thiol-Ene Ionogels with Octakis(methacryloxypropyl) Silsesquioxane
by: Aneta Lewandowska, et al.
Published: (2021-01-01)

Factors That Influence Base-Catalyzed Thiol-Ene Hydrogel Synthesis
by: Nolan Morrison, et al.
Published: (2023-11-01)

Thiol-Ene Reaction of Heparin Allyl Ester, Heparin 4-Vinylbenzyl Ester and Enoxaparin
by: Richard T. Taylor, et al.
Published: (2022-09-01)

Synthesis and shape memory behavior of hyperbranched polyimides from thiol-ene click reaction
by: Y. F. Lu, et al.
Published: (2020-02-01)

Intramolecular bridges formed by photoswitchable click amino acids
by: Christian Hoppmann, et al.
Published: (2012-06-01)

Off-Stoichiometry Thiol–Ene Polymers: Inclusion of Anchor Groups Using Allylsilanes
by: Kirill Puchnin, et al.
Published: (2023-03-01)

Amino acid-incorporated polymer network by thiol-ene polymerization
by: R. Yokose, et al.
Published: (2015-08-01)

Off-Stoichiometry Thiol–Enes Polymers Containing Silane Groups for Advanced Packaging Technologies
by: Kirill Puchnin, et al.
Published: (2022-05-01)

A Study on the Dual Thermo- and pH-Responsive Behaviors of Well-Defined Star-like Block Copolymers Synthesize by Combining of RAFT Polymerization and Thiol-Ene Click Reaction
by: Yan Xue, et al.
Published: (2022-04-01)

Thermal Degradation Behavior of Thiol-ene Composites Loaded with a Novel Silicone Flame Retardant
by: Haonan Chen, et al.
Published: (2022-10-01)

Hot Embossing of Micro-Pyramids into Thermoset Thiol-Ene Film
by: Dalius Jucius, et al.
Published: (2020-10-01)

Study of the Relationship between Haze Performance and Fractal Dimension in Micro-Sized Segregated Liquid Crystals Embedded in a Polymer Matrix Consisting of a Thiol-ene Prepolymer and a Multi-Functional Acrylate
by: Ju-Yong Kim, et al.
Published: (2021-12-01)