Cross-Coupling Synthesis of Methylallyl Alkenes: Scope Extension and Mechanistic Study

Cross-Coupling Synthesis of Methylallyl Alkenes: Scope Extension and Mechanistic Study

Cross-coupling reactions between 2-methyl-2-propen-1-ol and various boronic acids are used to obtain aromatic-(2-methylallyl) derivatives. However, deboronation or isomerization side reactions may occur for several boronic acids. We describe herein the synthesis of original alkenes with good yields...

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Bibliographic Details
Main Authors: Clémence Tabélé, Christophe Curti, Youssef Kabri, Nicolas Primas, Patrice Vanelle
Format: Article
Language:English
Published: MDPI AG 2015-12-01
Series:Molecules
Subjects:
palladium
cross-coupling reactions
boronic acids
allyl alcohol
Online Access:http://www.mdpi.com/1420-3049/20/12/19886

Internet

http://www.mdpi.com/1420-3049/20/12/19886

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