Cohalogenation of Allyl and Vinylsilanes using Polymer-bound Haloate(I)-Reagents

Cohalogenation of Allyl and Vinylsilanes using Polymer-bound Haloate(I)-Reagents

Polymer-supported electrophilic halogenate(I) complexes 2 and 3 promote smooth addition to vinyl and allylsilanes without loss of the silyl group. In conjunction with Amberlyst A26 (OH− -form) vinyl silanes are converted into epoxysilanes.

Bibliographic Details
Main Authors: Andreas Kirschning, Andreas Schönberger, Nuria Merayo, Georgia Sourkouni-Argirusi, Silvie Domann
Format: Article
Language:English
Published: MDPI AG 2001-01-01
Series:Molecules
Subjects:
Cohalogenation
allylsilane
vinylsilane
polymer-supported reagent
Online Access:http://www.mdpi.com/1420-3049/6/1/61/

Internet

http://www.mdpi.com/1420-3049/6/1/61/

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