Markovnikov-Type Hydrotrifluoromethylchalcogenation of Unactivated Terminal Alkenes with [Me<sub>4</sub>N][XCF<sub>3</sub>] (X = S, Se) and TfOH

Markovnikov-Type Hydrotrifluoromethylchalcogenation of Unactivated Terminal Alkenes with [Me<sub>4</sub>N][XCF<sub>3</sub>] (X = S, Se) and TfOH

The first Markovnikov-type hydrotrifluoromethylselenolation of unactivated terminal alkenes with the readily accessible [Me<sub>4</sub>N][SeCF<sub>3</sub>] reagent and the superacid TfOH is reported. The reaction proceeded at room temperature under catalyst- and additive-free...

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Bibliographic Details
Main Authors: Jin Shi, Cheng-Pan Zhang
Format: Article
Language:English
Published: MDPI AG 2020-10-01
Series:Molecules
Subjects:
hydrotrifluoromethylselenolation
hydrotrifluoromethylthiolation
Markovnikov-type
terminal alkene
superacid
Online Access:https://www.mdpi.com/1420-3049/25/19/4535

Internet

https://www.mdpi.com/1420-3049/25/19/4535

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