Phenomena and significance of intermediate spillover in electrocatalysis of oxygen and hydrogen electrode reactions

Phenomena and significance of intermediate spillover in electrocatalysis of oxygen and hydrogen electrode reactions

Altervalent hypo-d-oxides of transition metal series impose spontaneous dissociative adsorption of water molecules and pronounced membrane spillover transferring properties instantaneously resulting with corresponding bronze type (Pt/HxWO3) under cathodic, and/or its hydrated state (Pt/W(OH)6) r...

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Bibliographic Details
Main Authors: Jakšić Jelena M., Labou Diamantoula, Papakonstantinou Georgos D.
Format: Article
Language:English
Published: Association of Chemical Engineers of Serbia 2012-01-01
Series:Hemijska Industrija
Subjects:
spillover
effusion
primary oxide
nanostructured tungsten (or niobium
tantalum) bronze
hypo-hyper-d-d-interelectronic bonding
alterpolar electrocatalyst
alterpolar revertible cell
strong metal-support interaction
UPD double layer charging
self-catalytic H2O effect
Online Access:http://www.doiserbia.nb.rs/img/doi/0367-598X/2012/0367-598X1200005J.pdf

Internet

http://www.doiserbia.nb.rs/img/doi/0367-598X/2012/0367-598X1200005J.pdf

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