Crystal structures of bis[4-(dimethylamino)pyridinium] tetrakis(thiocyanato-κN)manganate(II) and tris[4-(dimethylamino)pyridinium] pentakis(thiocyanato-κN)manganate(II)

Crystal structures of bis[4-(dimethylamino)pyridinium] tetrakis(thiocyanato-κN)manganate(II) and tris[4-(dimethylamino)pyridinium] pentakis(thiocyanato-κN)manganate(II)

The crystal structures of the title salts, (C7H11N2)2[Mn(NCS)4] (1) and (C7H11N2)3[Mn(NCS)5] (2), consist of manganese(II) cations that are tetrahedrally (1) or trigonal–bipyramidally (2) coordinated to four or five terminal N-bonded thiocyanate ligands, respectively, into discrete anionic complexes...

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Bibliographic Details
Main Authors: Tristan Neumann, Inke Jess, Christian Näther
Format: Article
Language:English
Published: International Union of Crystallography 2018-01-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
discrete complexes
thiocyanatomanganate(II)
fivefold coordination
fourfold coordination
4-(dimethylamino)pyridine
hydrogen bonding
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989017017510

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http://scripts.iucr.org/cgi-bin/paper?S2056989017017510

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