Crystal structures of bis[4-(dimethylamino)pyridinium] tetrakis(thiocyanato-κN)manganate(II) and tris[4-(dimethylamino)pyridinium] pentakis(thiocyanato-κN)manganate(II)
The crystal structures of the title salts, (C7H11N2)2[Mn(NCS)4] (1) and (C7H11N2)3[Mn(NCS)5] (2), consist of manganese(II) cations that are tetrahedrally (1) or trigonal–bipyramidally (2) coordinated to four or five terminal N-bonded thiocyanate ligands, respectively, into discrete anionic complexes...
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| Language: | English |
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International Union of Crystallography
2018-01-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989017017510 |
| _version_ | 1818320842326540288 |
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| author | Tristan Neumann Inke Jess Christian Näther |
| author_facet | Tristan Neumann Inke Jess Christian Näther |
| author_sort | Tristan Neumann |
| collection | DOAJ |
| description | The crystal structures of the title salts, (C7H11N2)2[Mn(NCS)4] (1) and (C7H11N2)3[Mn(NCS)5] (2), consist of manganese(II) cations that are tetrahedrally (1) or trigonal–bipyramidally (2) coordinated to four or five terminal N-bonded thiocyanate ligands, respectively, into discrete anionic complexes. The negative charge is compensated by two (1) or three (2) 4-(dimethylamino)pyridinium cations, which are protonated at the pyridine N atom. The asymmetric unit of compound 1 consists of one anionic complex and two 4-(dimethylamino)pyridinium cations, whereas that of compound 2 consists of two anionic complexes and six 4-(dimethylamino)pyridinium cations, all of them located in general positions. These complexes are linked by N—H...S, C—H...S and C—H...N hydrogen-bonding interactions between the 4-(dimethylamino)pyridinium cations and the thiocyanate ligands into three-dimensional network structures. |
| first_indexed | 2024-12-13T10:31:26Z |
| format | Article |
| id | doaj.art-7ee24389b73a4bff9cd08cdd886f4134 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-13T10:31:26Z |
| publishDate | 2018-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-7ee24389b73a4bff9cd08cdd886f41342022-12-21T23:50:50ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902018-01-01741152010.1107/S2056989017017510wm5426Crystal structures of bis[4-(dimethylamino)pyridinium] tetrakis(thiocyanato-κN)manganate(II) and tris[4-(dimethylamino)pyridinium] pentakis(thiocyanato-κN)manganate(II)Tristan Neumann0Inke Jess1Christian Näther2Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth Strasse 2, D-24118 Kiel, GermanyInstitut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth Strasse 2, D-24118 Kiel, GermanyInstitut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth Strasse 2, D-24118 Kiel, GermanyThe crystal structures of the title salts, (C7H11N2)2[Mn(NCS)4] (1) and (C7H11N2)3[Mn(NCS)5] (2), consist of manganese(II) cations that are tetrahedrally (1) or trigonal–bipyramidally (2) coordinated to four or five terminal N-bonded thiocyanate ligands, respectively, into discrete anionic complexes. The negative charge is compensated by two (1) or three (2) 4-(dimethylamino)pyridinium cations, which are protonated at the pyridine N atom. The asymmetric unit of compound 1 consists of one anionic complex and two 4-(dimethylamino)pyridinium cations, whereas that of compound 2 consists of two anionic complexes and six 4-(dimethylamino)pyridinium cations, all of them located in general positions. These complexes are linked by N—H...S, C—H...S and C—H...N hydrogen-bonding interactions between the 4-(dimethylamino)pyridinium cations and the thiocyanate ligands into three-dimensional network structures.http://scripts.iucr.org/cgi-bin/paper?S2056989017017510crystal structurediscrete complexesthiocyanatomanganate(II)fivefold coordinationfourfold coordination4-(dimethylamino)pyridinehydrogen bonding |
| spellingShingle | Tristan Neumann Inke Jess Christian Näther Crystal structures of bis[4-(dimethylamino)pyridinium] tetrakis(thiocyanato-κN)manganate(II) and tris[4-(dimethylamino)pyridinium] pentakis(thiocyanato-κN)manganate(II) Acta Crystallographica Section E: Crystallographic Communications crystal structure discrete complexes thiocyanatomanganate(II) fivefold coordination fourfold coordination 4-(dimethylamino)pyridine hydrogen bonding |
| title | Crystal structures of bis[4-(dimethylamino)pyridinium] tetrakis(thiocyanato-κN)manganate(II) and tris[4-(dimethylamino)pyridinium] pentakis(thiocyanato-κN)manganate(II) |
| title_full | Crystal structures of bis[4-(dimethylamino)pyridinium] tetrakis(thiocyanato-κN)manganate(II) and tris[4-(dimethylamino)pyridinium] pentakis(thiocyanato-κN)manganate(II) |
| title_fullStr | Crystal structures of bis[4-(dimethylamino)pyridinium] tetrakis(thiocyanato-κN)manganate(II) and tris[4-(dimethylamino)pyridinium] pentakis(thiocyanato-κN)manganate(II) |
| title_full_unstemmed | Crystal structures of bis[4-(dimethylamino)pyridinium] tetrakis(thiocyanato-κN)manganate(II) and tris[4-(dimethylamino)pyridinium] pentakis(thiocyanato-κN)manganate(II) |
| title_short | Crystal structures of bis[4-(dimethylamino)pyridinium] tetrakis(thiocyanato-κN)manganate(II) and tris[4-(dimethylamino)pyridinium] pentakis(thiocyanato-κN)manganate(II) |
| title_sort | crystal structures of bis 4 dimethylamino pyridinium tetrakis thiocyanato κn manganate ii and tris 4 dimethylamino pyridinium pentakis thiocyanato κn manganate ii |
| topic | crystal structure discrete complexes thiocyanatomanganate(II) fivefold coordination fourfold coordination 4-(dimethylamino)pyridine hydrogen bonding |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989017017510 |
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