Crystal structure of {3-[3,5-bis(2,6-dimethylphenyl)-1,2-phenylene]-1-(2,6,2′′,6′′-tetramethyl-1,1′:3′,1′′-terphenyl-5′-yl)imidazol-2-ylidene}chlorido(η6-p-cymene)ruthenium(II) benzene disolvate

Crystal structure of {3-[3,5-bis(2,6-dimethylphenyl)-1,2-phenylene]-1-(2,6,2′′,6′′-tetramethyl-1,1′:3′,1′′-terphenyl-5′-yl)imidazol-2-ylidene}chlorido(η6-p-cymene)ruthenium(II) benzene disolvate

The title compound, [Ru(C47H43N2)Cl(C10H14)]·2C6H6, crystallized with two independent molecules of benzene. One of the N-aryl moieties of the N-heterocyclic carbene (NHC) ligand underwent cyclometallation to form a five-membered ruthenacycle. The complex has a three-legged piano-stool structure with...

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Bibliographic Details
Main Authors: Shohei Sase, Yuriko Ikehara, Kei Goto
Format: Article
Language:English
Published: International Union of Crystallography 2014-12-01
Series:Acta Crystallographica Section E
Subjects:
crystal structure
ruthenium(II) complex
ruthenacycle
N-heterocyclic carbene
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681402399X

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http://scripts.iucr.org/cgi-bin/paper?S160053681402399X

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