Crystal structure of {3-[3,5-bis(2,6-dimethylphenyl)-1,2-phenylene]-1-(2,6,2′′,6′′-tetramethyl-1,1′:3′,1′′-terphenyl-5′-yl)imidazol-2-ylidene}chlorido(η6-p-cymene)ruthenium(II) benzene disolvate
The title compound, [Ru(C47H43N2)Cl(C10H14)]·2C6H6, crystallized with two independent molecules of benzene. One of the N-aryl moieties of the N-heterocyclic carbene (NHC) ligand underwent cyclometallation to form a five-membered ruthenacycle. The complex has a three-legged piano-stool structure with...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014-12-01
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| Series: | Acta Crystallographica Section E |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681402399X |
| _version_ | 1828128789627928576 |
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| author | Shohei Sase Yuriko Ikehara Kei Goto |
| author_facet | Shohei Sase Yuriko Ikehara Kei Goto |
| author_sort | Shohei Sase |
| collection | DOAJ |
| description | The title compound, [Ru(C47H43N2)Cl(C10H14)]·2C6H6, crystallized with two independent molecules of benzene. One of the N-aryl moieties of the N-heterocyclic carbene (NHC) ligand underwent cyclometallation to form a five-membered ruthenacycle. The complex has a three-legged piano-stool structure with two C atoms incorporated in the five-membered ruthenacycle and a Cl atom as legs. The ruthenacycle is essentially coplanar with the imidazole ring of the NHC ligand, making a dihedral angle of 0.85 (8)°. |
| first_indexed | 2024-04-11T16:10:52Z |
| format | Article |
| id | doaj.art-7ef0049c230846309dd252f6af06ec64 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T16:10:52Z |
| publishDate | 2014-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-7ef0049c230846309dd252f6af06ec642022-12-22T04:14:42ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-12-017012m394m39410.1107/S160053681402399Xis5379Crystal structure of {3-[3,5-bis(2,6-dimethylphenyl)-1,2-phenylene]-1-(2,6,2′′,6′′-tetramethyl-1,1′:3′,1′′-terphenyl-5′-yl)imidazol-2-ylidene}chlorido(η6-p-cymene)ruthenium(II) benzene disolvateShohei Sase0Yuriko Ikehara1Kei Goto2Department of Chemistry, Graduate School of Science and Engineering, Tokyo Instiute of Technology, Ookayama, Meguro-ku, Tokyo, 152-8551, JapanDepartment of Chemistry, Graduate School of Science and Engineering, Tokyo Instiute of Technology, Ookayama, Meguro-ku, Tokyo, 152-8551, JapanDepartment of Chemistry, Graduate School of Science and Engineering, Tokyo Instiute of Technology, Ookayama, Meguro-ku, Tokyo, 152-8551, JapanThe title compound, [Ru(C47H43N2)Cl(C10H14)]·2C6H6, crystallized with two independent molecules of benzene. One of the N-aryl moieties of the N-heterocyclic carbene (NHC) ligand underwent cyclometallation to form a five-membered ruthenacycle. The complex has a three-legged piano-stool structure with two C atoms incorporated in the five-membered ruthenacycle and a Cl atom as legs. The ruthenacycle is essentially coplanar with the imidazole ring of the NHC ligand, making a dihedral angle of 0.85 (8)°.http://scripts.iucr.org/cgi-bin/paper?S160053681402399Xcrystal structureruthenium(II) complexruthenacycleN-heterocyclic carbene |
| spellingShingle | Shohei Sase Yuriko Ikehara Kei Goto Crystal structure of {3-[3,5-bis(2,6-dimethylphenyl)-1,2-phenylene]-1-(2,6,2′′,6′′-tetramethyl-1,1′:3′,1′′-terphenyl-5′-yl)imidazol-2-ylidene}chlorido(η6-p-cymene)ruthenium(II) benzene disolvate Acta Crystallographica Section E crystal structure ruthenium(II) complex ruthenacycle N-heterocyclic carbene |
| title | Crystal structure of {3-[3,5-bis(2,6-dimethylphenyl)-1,2-phenylene]-1-(2,6,2′′,6′′-tetramethyl-1,1′:3′,1′′-terphenyl-5′-yl)imidazol-2-ylidene}chlorido(η6-p-cymene)ruthenium(II) benzene disolvate |
| title_full | Crystal structure of {3-[3,5-bis(2,6-dimethylphenyl)-1,2-phenylene]-1-(2,6,2′′,6′′-tetramethyl-1,1′:3′,1′′-terphenyl-5′-yl)imidazol-2-ylidene}chlorido(η6-p-cymene)ruthenium(II) benzene disolvate |
| title_fullStr | Crystal structure of {3-[3,5-bis(2,6-dimethylphenyl)-1,2-phenylene]-1-(2,6,2′′,6′′-tetramethyl-1,1′:3′,1′′-terphenyl-5′-yl)imidazol-2-ylidene}chlorido(η6-p-cymene)ruthenium(II) benzene disolvate |
| title_full_unstemmed | Crystal structure of {3-[3,5-bis(2,6-dimethylphenyl)-1,2-phenylene]-1-(2,6,2′′,6′′-tetramethyl-1,1′:3′,1′′-terphenyl-5′-yl)imidazol-2-ylidene}chlorido(η6-p-cymene)ruthenium(II) benzene disolvate |
| title_short | Crystal structure of {3-[3,5-bis(2,6-dimethylphenyl)-1,2-phenylene]-1-(2,6,2′′,6′′-tetramethyl-1,1′:3′,1′′-terphenyl-5′-yl)imidazol-2-ylidene}chlorido(η6-p-cymene)ruthenium(II) benzene disolvate |
| title_sort | crystal structure of 3 3 5 bis 2 6 dimethylphenyl 1 2 phenylene 1 2 6 2 6 tetramethyl 1 1 3 1 terphenyl 5 yl imidazol 2 ylidene chlorido η6 p cymene ruthenium ii benzene disolvate |
| topic | crystal structure ruthenium(II) complex ruthenacycle N-heterocyclic carbene |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053681402399X |
| work_keys_str_mv | AT shoheisase crystalstructureof335bis26dimethylphenyl12phenylene12626tetramethyl1131terphenyl5ylimidazol2ylidenechloridoē6pcymenerutheniumiibenzenedisolvate AT yurikoikehara crystalstructureof335bis26dimethylphenyl12phenylene12626tetramethyl1131terphenyl5ylimidazol2ylidenechloridoē6pcymenerutheniumiibenzenedisolvate AT keigoto crystalstructureof335bis26dimethylphenyl12phenylene12626tetramethyl1131terphenyl5ylimidazol2ylidenechloridoē6pcymenerutheniumiibenzenedisolvate |