First application of chiral phosphotriesters in asymmetric metal catalysis: enantioselective Zn-catalyzed hydrosilylation of ketones in the presence of BINOL-derived phosphates
Chiral phosphotriesters are an unexplored class of ligands in metal catalysis. We wish to disclose herein the foremost application of novel chiral BINOL-derived mono- and bisphosphates in asymmetric zinc-catalyzed hydrosilylation of ketones. Corresponding alcohols were obtained in up to 92% yield an...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Académie des sciences
2021-03-01
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| Series: | Comptes Rendus. Chimie |
| Subjects: | |
| Online Access: | https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.67/ |