Most Earth-surface calcites precipitate out of isotopic equilibrium

Isotopic thermometry of carbonate minerals postulates that their composition reflects thermodynamic equilibrium constants. Here the authors constrain equilibrium relationships between temperature, 18O/16O and clumped isotopes and find that most natural calcites form out of isotopic equilibrium.

Bibliographic Details
Main Authors: M. Daëron, R. N. Drysdale, M. Peral, D. Huyghe, D. Blamart, T. B. Coplen, F. Lartaud, G. Zanchetta
Format: Article
Language:English
Published: Nature Portfolio 2019-01-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-019-08336-5