First example of organocatalysis by cathodic N-heterocyclic carbene generation and accumulation using a divided electrochemical flow cell

First example of organocatalysis by cathodic N-heterocyclic carbene generation and accumulation using a divided electrochemical flow cell

In this paper we present the first electrochemical generation of NHC carried out in a divided flow cell. The flow cell operated in the recycle mode. The need for a divided cell derived from the anodic electroactivity of the electrogenerated carbene. In order to have NHC accumulation in the catholyte...

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Bibliographic Details
Main Authors: Daniele Rocco, Ana A. Folgueiras-Amador, Richard C. D. Brown, Marta Feroci
Format: Article
Language:English
Published: Beilstein-Institut 2022-08-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
breslow intermediate
cathodic reduction
flow electrochemistry
n-heterocyclic carbene
oxidative esterification
Online Access:https://doi.org/10.3762/bjoc.18.98

Internet

https://doi.org/10.3762/bjoc.18.98

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