Intermolecular hydrogen bonding in N-methyl-N′-(pyridin-2-yl)benzene-1,2-diamine

Intermolecular hydrogen bonding in N-methyl-N′-(pyridin-2-yl)benzene-1,2-diamine

The structure of N-methyl-N′-(pyridin-2-yl)benzene-1,2-diamine, C12H13N3, at 123 K has orthorhombic (Pna21) symmetry. The title compound displays an unexpected proton-splitting pattern when studied by 1H NMR spectroscopy. The X-ray crystallography analysis determined this to be caused by strong dual...

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Bibliographic Details
Main Authors: Gavin Collis, Alex Bilyk, Ueno Kazanori, Craig M. Forsyth
Format: Article
Language:English
Published: International Union of Crystallography 2022-10-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
hydrogen bonding
dimerization
heterocycles.
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989022009173

Internet

http://scripts.iucr.org/cgi-bin/paper?S2056989022009173

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