Crystal structure, spectral, thermo-gravimetric and antibacterial properties of Zn(Ⅱ) ofloxacin complex(氧氟沙星锌配合物的结构、光谱性质与抗菌活性)
合成了以氧氟沙星(ofloxacin，ofo)为配体的锌（Ⅱ)配合物Zn(ofo)2 (H2O) • 2H2O，报道了锌配合物的单晶结构：三斜晶系，P-1空间群，晶胞参数为a=9.306(1)Å，b=11.331(1)Å，c=17.787 (2) Å，α= 92.667(1)°，β = 94.898(2)°, γ= 92.071(2)°，V= 1865.1(3)Å3，Z=2，Dc = 1.496 mg • m-3，畸变的四方锥形配位几何构型，其中锥顶上的氧原子来自水分子，锥底的4个氧原子来自两个氧氟沙星的羧酸根和酮基；探讨了该配合物的红外光谱、紫外-可见光谱、固体荧光光谱性质，对配合物的热稳定...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | zho |
| Published: |
Zhejiang University Press
2011-01-01
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| Series: | Zhejiang Daxue xuebao. Lixue ban |
| Subjects: | |
| Online Access: | https://doi.org/10.3785/j.issn.1008-9497.2011.01.017 |