Large Magnetic Polyoxometalates Containing the Cobalt Cubane ‘[CoIIICo3II(OH)3(H2O)6–m(PW9O34)]3−' (m = 3 or 5) as a Subunit

Large Magnetic Polyoxometalates Containing the Cobalt Cubane ‘[CoIIICo3II(OH)3(H2O)6–m(PW9O34)]3−' (m = 3 or 5) as a Subunit

A synthetic procedure is presented to construct new magnetic polyoxometalates (POMs) containing one or two subunits of ‘[CoIIICo3II(OH)3(H2O)6−m(PW9O34)]3−' (m = 3 or 5). The substitution of the water ligands present in these subunits by oxo or hydroxo ligands belonging to other POM fragments,...

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Bibliographic Details
Main Authors: Yan Duan, Juan M. Clemente-Juan, Carlos Giménez-Saiz, Eugenio Coronado
Format: Article
Language:English
Published: Frontiers Media S.A. 2018-06-01
Series:Frontiers in Chemistry
Subjects:
polyoxometalate
magnetism
cubane cluster
cobalt
crystal structure
Online Access:https://www.frontiersin.org/article/10.3389/fchem.2018.00231/full

Internet

https://www.frontiersin.org/article/10.3389/fchem.2018.00231/full

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