Bipolar Switching Properties of GdO<sub>x</sub>:SiO<sub>2</sub> Thin Film Resistive Random Access Memory Using Co-Sputtering Technology

Using two kinds of targets (gallium and silicon dioxide) and the rf magnetron sputtering deposited technique, GdO<sub>x</sub>:SiO<sub>2</sub> thin film RRAM devices were deposited on TiN/Si substrate to form a metal–insulator–metal (MIM) structure. In addition, different oxyg...

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Main Authors: Kai-Huang Chen, Chien-Min Cheng, Na-Fu Wang, Jia-Cheng Zhou, Mei-Li Chen
Format: Article
Language:English
Published: MDPI AG 2023-01-01
Series:Crystals
Subjects:
Online Access:https://www.mdpi.com/2073-4352/13/2/156
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author Kai-Huang Chen
Chien-Min Cheng
Na-Fu Wang
Jia-Cheng Zhou
Mei-Li Chen
author_facet Kai-Huang Chen
Chien-Min Cheng
Na-Fu Wang
Jia-Cheng Zhou
Mei-Li Chen
author_sort Kai-Huang Chen
collection DOAJ
description Using two kinds of targets (gallium and silicon dioxide) and the rf magnetron sputtering deposited technique, GdO<sub>x</sub>:SiO<sub>2</sub> thin film RRAM devices were deposited on TiN/Si substrate to form a metal–insulator–metal (MIM) structure. In addition, different oxygen concentrations and rf sputtering power parameters were prepared for the GdO<sub>x</sub>:SiO<sub>2</sub> thin films. Decrease of the defects and oxygen vacancies of the GdO<sub>x</sub>:SiO<sub>2</sub> thin films were used and repaired by rapid thermal annealing technology. Indium tin oxide (ITO) as the top electrode on the GdO<sub>x</sub>:SiO<sub>2</sub> thin film was prepared by the physical vapor deposition (PVD) method, and ITO/GdO<sub>x</sub>:SiO<sub>2</sub>/TiN/Si structures of the GdO<sub>x</sub>:SiO<sub>2</sub> thin films’ RRAM devices were also made. In addition, the current–voltage curves and devices’ endurance properties were measured by an impedance analyzer. Finally, the crystalline style, the preferred phase, the grain size, and surface microstructure of the thin films were analyzed and observed from X-ray diffraction and field emission scanning electron microscope measurements.
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spelling doaj.art-81596555d4a544afad0162af0850fe662023-11-16T19:54:13ZengMDPI AGCrystals2073-43522023-01-0113215610.3390/cryst13020156Bipolar Switching Properties of GdO<sub>x</sub>:SiO<sub>2</sub> Thin Film Resistive Random Access Memory Using Co-Sputtering TechnologyKai-Huang Chen0Chien-Min Cheng1Na-Fu Wang2Jia-Cheng Zhou3Mei-Li Chen4Department of Electronic Engineering, Center for Environmental Toxin and Emerging-Contaminant Research, Super Micro Mass Research & Technology Center, Cheng Shiu University, Chengcing Rd., Niaosong District, Kaohsiung City 83347, TaiwanDepartment of Electronic Engineering, Southern Taiwan University of Science and Technology, Tainan 710301, TaiwanDepartment of Electronic Engineering, Center for Environmental Toxin and Emerging-Contaminant Research, Super Micro Mass Research & Technology Center, Cheng Shiu University, Chengcing Rd., Niaosong District, Kaohsiung City 83347, TaiwanDepartment of Electronic Engineering, Southern Taiwan University of Science and Technology, Tainan 710301, TaiwanDepartment of Electro-Optical Engineering, Southern Taiwan University of Science and Technology, Tainan 710301, TaiwanUsing two kinds of targets (gallium and silicon dioxide) and the rf magnetron sputtering deposited technique, GdO<sub>x</sub>:SiO<sub>2</sub> thin film RRAM devices were deposited on TiN/Si substrate to form a metal–insulator–metal (MIM) structure. In addition, different oxygen concentrations and rf sputtering power parameters were prepared for the GdO<sub>x</sub>:SiO<sub>2</sub> thin films. Decrease of the defects and oxygen vacancies of the GdO<sub>x</sub>:SiO<sub>2</sub> thin films were used and repaired by rapid thermal annealing technology. Indium tin oxide (ITO) as the top electrode on the GdO<sub>x</sub>:SiO<sub>2</sub> thin film was prepared by the physical vapor deposition (PVD) method, and ITO/GdO<sub>x</sub>:SiO<sub>2</sub>/TiN/Si structures of the GdO<sub>x</sub>:SiO<sub>2</sub> thin films’ RRAM devices were also made. In addition, the current–voltage curves and devices’ endurance properties were measured by an impedance analyzer. Finally, the crystalline style, the preferred phase, the grain size, and surface microstructure of the thin films were analyzed and observed from X-ray diffraction and field emission scanning electron microscope measurements.https://www.mdpi.com/2073-4352/13/2/156RRAMGdO<sub>x</sub>:SiO<sub>2</sub>bipolar resistive switchingphysical propertiesrf power
spellingShingle Kai-Huang Chen
Chien-Min Cheng
Na-Fu Wang
Jia-Cheng Zhou
Mei-Li Chen
Bipolar Switching Properties of GdO<sub>x</sub>:SiO<sub>2</sub> Thin Film Resistive Random Access Memory Using Co-Sputtering Technology
Crystals
RRAM
GdO<sub>x</sub>:SiO<sub>2</sub>
bipolar resistive switching
physical properties
rf power
title Bipolar Switching Properties of GdO<sub>x</sub>:SiO<sub>2</sub> Thin Film Resistive Random Access Memory Using Co-Sputtering Technology
title_full Bipolar Switching Properties of GdO<sub>x</sub>:SiO<sub>2</sub> Thin Film Resistive Random Access Memory Using Co-Sputtering Technology
title_fullStr Bipolar Switching Properties of GdO<sub>x</sub>:SiO<sub>2</sub> Thin Film Resistive Random Access Memory Using Co-Sputtering Technology
title_full_unstemmed Bipolar Switching Properties of GdO<sub>x</sub>:SiO<sub>2</sub> Thin Film Resistive Random Access Memory Using Co-Sputtering Technology
title_short Bipolar Switching Properties of GdO<sub>x</sub>:SiO<sub>2</sub> Thin Film Resistive Random Access Memory Using Co-Sputtering Technology
title_sort bipolar switching properties of gdo sub x sub sio sub 2 sub thin film resistive random access memory using co sputtering technology
topic RRAM
GdO<sub>x</sub>:SiO<sub>2</sub>
bipolar resistive switching
physical properties
rf power
url https://www.mdpi.com/2073-4352/13/2/156
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