Kinetics and Energetics of Thermal Cis-Trans Isomerization of a Resonance-Activated Azobenzene in BMIM-Based Ionic Liquids for PF6−/Tf2N− Comparison

Kinetics and Energetics of Thermal Cis-Trans Isomerization of a Resonance-Activated Azobenzene in BMIM-Based Ionic Liquids for PF6−/Tf2N− Comparison

BMIM PF6 (1-butyl-3-methylimidazolium hexafluorophosphate) and BMIM Tf2N (1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide) are two conventional room-temperature ionic liquids widely employed and investigated as reaction media. Despite the presence of the same imidazolium ring in their...

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Bibliographic Details
Main Authors: Guido Angelini, Cristina Campestre, Luca Scotti, Carla Gasbarri
Format: Article
Language:English
Published: MDPI AG 2017-07-01
Series:Molecules
Subjects:
imidazolium ionic liquids
4-methoxyazobenzene
rotation
Arrhenius plot
Eyring plot
Online Access:https://www.mdpi.com/1420-3049/22/8/1273

Internet

https://www.mdpi.com/1420-3049/22/8/1273

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