Investigation of the key active intermediate for the synthesis of 1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane: Hydrolysis and nitrolysis of 1-acetoxymethyl-3,5,7-trinitro-1,3,5,7-tetraazacyclooctane

Investigation of the key active intermediate for the synthesis of 1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane: Hydrolysis and nitrolysis of 1-acetoxymethyl-3,5,7-trinitro-1,3,5,7-tetraazacyclooctane

The problem whether 1-hydroxylmethyl-3,5,7-trinitro-1,3,5,7-tetraazacyclooctane is the key active intermediate for the synthesis of 1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane (HMX) from urotropine or 3,7-dinitro-1,3,5,7-tetraazabicyclo[3.3.1]nonane (DPT) remains to be illuminated for decades. In...

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Bibliographic Details
Main Authors: Yu Zhang, Zishuai Xu, Luyao Zhang, Guangyuan Zhang, Dan He, Xiaolong Wang, Jian Ruan, Delong Zhang, Guoliang Jin, Xiaoping Ma, Xiaoliang He, Yanming Xu, Ying He, Jun Luo
Format: Article
Language:English
Published: KeAi Communications Co. Ltd. 2020-09-01
Series:Energetic Materials Frontiers
Subjects:
1,3,5,7-Tetranitro-1,3,5,7-tetraazacyclooctane (HMX)
1-Acetoxymethyl-3,5,7-trinitro-1,3,5,7-tetraazacyclooctane (PHX)
1-Hydroxymethyl-3,5,7-trinitro-1,3,5,7-tetraazacyclooctane
Reaction mechanism
Nitrolysis
Nitrosolysis
Online Access:http://www.sciencedirect.com/science/article/pii/S2666647220300154

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http://www.sciencedirect.com/science/article/pii/S2666647220300154

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