Regioselective Arylation of Amidoaryne Precursors via Ag‐Mediated Intramolecular Oxy‐Argentation

Regioselective Arylation of Amidoaryne Precursors via Ag‐Mediated Intramolecular Oxy‐Argentation

Abstract An unprecedented silver‐mediated intramolecular oxy‐argentation of 3‐amidoaryne precursors that quickly generates a heteroarylsilver species is developed. AgF acts as both a stoichiometric fluoride source and a reagent for the formation of a benzoxazolylsilver intermediate via aryne generat...

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Bibliographic Details
Main Authors: Yong‐Ju Kwon, Ye‐Jin Kong, Min‐Jung Lee, Eun‐Hye Lim, Jaesung Kwak, Won‐Suk Kim
Format: Article
Language:English
Published: Wiley 2024-05-01
Series:Advanced Science
Subjects:
amidobenzyne precursors
aryne
bimetallic cross‐coupling
oxy‐argentation
regioselective arylation
Online Access:https://doi.org/10.1002/advs.202308829

Internet

https://doi.org/10.1002/advs.202308829

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