Cyclometallated Palladium(II) Complexes: An Approach to the First Dinuclear Bis(iminophosphorane)phosphane-[C,N,S] Metallacycle

Cyclometallated Palladium(II) Complexes: An Approach to the First Dinuclear Bis(iminophosphorane)phosphane-[C,N,S] Metallacycle

Treatment of bis(iminophosphorane)phosphane ligands <b>2a</b>–<b>2e</b> with Li<sub>2</sub>PdCl<sub>4</sub> gave a set of novel diphosphane-derived complexes bearing two metallacycle rings, each one enclosing a P=N double bond: the unprecedented bis(im...

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Bibliographic Details
Main Authors: Marcos Rúa-Sueiro, Paula Munín-Cruz, Adolfo Fernández, Juan M. Ortigueira, María Teresa Pereira, José M. Vila
Format: Article
Language:English
Published: MDPI AG 2022-10-01
Series:Molecules
Subjects:
cyclometallation
palladium
iminophosphoranes
NMR
crystal structure
Online Access:https://www.mdpi.com/1420-3049/27/20/7043

Internet

https://www.mdpi.com/1420-3049/27/20/7043

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