Theoretical study on the insertion reaction of phosphenium cation and azirane

The mechanism of the insertion reaction between the phosphenium cation and azirane has been investigated theoretically in order to better understand the reactivity for the valence isoelectronic of carbene. The phosphenium cation acts as an electrophilic reagent and accepts the σ electrons of azirane...

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Bibliographic Details
Main Authors: Gu Jinsong, Zhao Xiaodong, Liu Shankui, Tan Xiaojun
Format: Article
Language:English
Published: Serbian Chemical Society 2022-01-01
Series:Journal of the Serbian Chemical Society
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/0352-5139/2022/0352-51392200021G.pdf