Trans-Selective Rhodium Catalysed Conjugate Addition of Organoboron Reagents to Dihydropyranones

Trans-Selective Rhodium Catalysed Conjugate Addition of Organoboron Reagents to Dihydropyranones

The selective synthesis of 2,6-trans-tetrahydropyran derivatives employing the rhodium catalysed addition of organoboron reagents to dihydropyranone templates, derived from a zinc-catalysed hetero-Diels-Alder reaction, is reported. The addition of both arylboronic acids and potassium alkenyltrifluor...

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Bibliographic Details
Main Authors: Hannah J. Edwards, Sean Goggins, Christopher G. Frost
Format: Article
Language:English
Published: MDPI AG 2015-04-01
Series:Molecules
Subjects:
boronic acids
conjugate addition
rhodium
tetrahydropyran
Online Access:http://www.mdpi.com/1420-3049/20/4/6153

Internet

http://www.mdpi.com/1420-3049/20/4/6153

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