Synthesis and Magnetic Properties of a Copper Cube: [Cu4(OH)4(C16H18N2)4]4+ (ClO4)4 C3H6O [C16H18N2=(E)‐1,6‐[Di(pyridin‐4‐yl)hex‐3‐ene]

Synthesis and Magnetic Properties of a Copper Cube: [Cu4(OH)4(C16H18N2)4]4+ (ClO4)4 C3H6O [C16H18N2=(E)‐1,6‐[Di(pyridin‐4‐yl)hex‐3‐ene]

Abstract The synthesis of a Cu4(OH)4 cube which is coordinated by four molecules of the dipyridyl ligand 1,6‐[di(pyridin‐4‐yl)hex‐3‐ene] is reported. This compound has a trans double bond which restricts the conformational freedom of the ligand and favours coordination within a unique copper cube. T...

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Bibliographic Details
Main Authors: Dr. M. John Plater, Amara Darr, Catriona Crawford, Craig Murray, Struan Simpson, Prof. William T. A. Harrison, Prof. Juan M. Clemente‐Juan
Format: Article
Language:English
Published: Wiley-VCH 2019-09-01
Series:ChemistryOpen
Subjects:
copper(II) perchlorate
magnetic properties
Jahn-Teller distortion
clusters
Online Access:https://doi.org/10.1002/open.201900260

Internet

https://doi.org/10.1002/open.201900260

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