Vinylation of a Secondary Amine Core with Calcium Carbide for Efficient Post-Modification and Access to Polymeric Materials

Vinylation of a Secondary Amine Core with Calcium Carbide for Efficient Post-Modification and Access to Polymeric Materials

We developed a simple and efficient strategy to access N-vinyl secondary amines of various naturally occurring materials using readily available solid acetylene reagents (calcium carbide, KF, and KOH). Pyrrole, pyrazole, indoles, carbazoles, and diarylamines were successfully vinylated in good yield...

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Bibliographic Details
Main Authors: Konstantin S. Rodygin, Alexander S. Bogachenkov, Valentine P. Ananikov
Format: Article
Language:English
Published: MDPI AG 2018-03-01
Series:Molecules
Subjects:
acetylene
calcium carbide
vinylation
olanzapine
functionalization
Online Access:http://www.mdpi.com/1420-3049/23/3/648

Internet

http://www.mdpi.com/1420-3049/23/3/648

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