Kinetic and mechanistic investigations of chlorocomplex of Ru(III) and Ir(III) catalyzed oxidation of d-fructose by N-bromophthalimide in acidic medium

Kinetic and mechanistic investigations of chlorocomplex of Ru(III) and Ir(III) catalyzed oxidation of d-fructose by N-bromophthalimide in acidic medium

The kinetic and mechanistic studies of Ru(III) and Ir(III) homogeneously catalyzed oxidation of d-fructose (d-fru) by N-bromophthalimide (NBP) in the presence of aqueous perchloric acid medium have been made at 303 K using mercuric acetate as Br− ion scavenger. The stoichiometry and the oxidation pr...

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Bibliographic Details
Main Authors: Neerja Sachdev, Ajaya Kumar Singh, Alpa Shrivastava, Yokraj Katre
Format: Article
Language:English
Published: Elsevier 2016-09-01
Series:Journal of Saudi Chemical Society
Subjects:
Kinetics
Oxidation
N-bromophthalimide (NBP)
d-fructose (d-fru)
Ru(III) chloride
Ir(III) chloride
Phthalimide (NHP)
Online Access:http://www.sciencedirect.com/science/article/pii/S1319610312001950

Internet

http://www.sciencedirect.com/science/article/pii/S1319610312001950

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