Exploring the role of halogen bonding in iodonium ylides: insights into unexpected reactivity and reaction control

Halogen bonding is commonly found with iodine-containing molecules, and it arises when Lewis bases interact with iodine’s σ-holes. Halogen bonding and σ-holes have been encountered in numerous monovalent and hypervalent iodine-containing compounds, and in 2022 σ-holes were computationally confirmed...

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Bibliographic Details
Main Authors: Carlee A. Montgomery, Graham K. Murphy
Format: Article
Language:English
Published: Beilstein-Institut 2023-08-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.19.86