Exploring the role of halogen bonding in iodonium ylides: insights into unexpected reactivity and reaction control

Exploring the role of halogen bonding in iodonium ylides: insights into unexpected reactivity and reaction control

Halogen bonding is commonly found with iodine-containing molecules, and it arises when Lewis bases interact with iodine’s σ-holes. Halogen bonding and σ-holes have been encountered in numerous monovalent and hypervalent iodine-containing compounds, and in 2022 σ-holes were computationally confirmed...

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Bibliographic Details
Main Authors:	Carlee A. Montgomery, Graham K. Murphy
Format:	Article
Language:	English
Published:	Beilstein-Institut 2023-08-01
Series:	Beilstein Journal of Organic Chemistry
Subjects:	electron donor–acceptor complex halogen bonding σ-holes iodonium ylides ortho-effect
Online Access:	https://doi.org/10.3762/bjoc.19.86

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