Cluster Salts [Nb6Cl12(HIm)6]An (with HIm=1H‐imidazole and A=Mineral Acid Anion, n=1 or 2) Made in and with Brønsted‐basic Ionic Liquids and Liquid Mixtures
Abstract Four new hexanuclear niobium cluster compounds of the general formula [Nb6Cl12(HIm)6](A)n ⋅ x(solvent molecule) (HIm=1H‐imidazole, A=mineral acid anion, Cl− (n=2) (1), (SO4)2− (n=1) (2), (CrO4)2− (n=1) (3), and (HAsO4)2− (n=1) (4)) were prepared. Their synthesis can be done in basic ionic l...
Main Authors: | , |
---|---|
Format: | Article |
Language: | English |
Published: |
Wiley-VCH
2021-02-01
|
Series: | ChemistryOpen |
Subjects: | |
Online Access: | https://doi.org/10.1002/open.202000266 |