(6-Hydroxy-2-{[2-(N-methylcarbamothiolyl)hydrazin-1-ylidene-κ2N1,S]methyl}phenolato-κO1)(triphenylphosphane-κP)nickel(II) chloride
The deprotonated Schiff base ligand in the title salt, [Ni(C9H10N3O2S)(C18H15P)]Cl, functions as an N,O,S-chelating anion to the phosphine-coordinated nickel(II) atom, which exists in a distorted square-planar geometry. The hydroxy group forms an intramolecular O—H...O hydrogen bond. T...
Main Authors: | , , |
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Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2010-11-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810039292 |