(6-Hydroxy-2-{[2-(N-methylcarbamothiolyl)hydrazin-1-ylidene-κ2N1,S]methyl}phenolato-κO1)(triphenylphosphane-κP)nickel(II) chloride

The deprotonated Schiff base ligand in the title salt, [Ni(C9H10N3O2S)(C18H15P)]Cl, functions as an N,O,S-chelating anion to the phosphine-coordinated nickel(II) atom, which exists in a distorted square-planar geometry. The hydroxy group forms an intramolecular O—H...O hydrogen bond. T...

Full description

Bibliographic Details
Main Authors: Hana Bashir Shawish, M. Jamil Maah, Seik Weng Ng
Format: Article
Language:English
Published: International Union of Crystallography 2010-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810039292