Phenylacetylene and Carbon Dioxide Activation by an Organometallic Samarium Complex

Small molecule activation is a topic of growing importance and the use of low-valent f-elements to perform these reactions is nowadays well established. The complex Cptt2Sm(thf) (1, Cptt = 1,3-(tBu)2Cp) is shown to activate the alkyne C–H bond of phenylacetylene to form the Cptt2Sm(C&e...

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Bibliographic Details
Main Authors: Violaine Goudy, Mathieu Xémard, Simon Karleskind, Marie Cordier, Carlos Alvarez Lamsfus, Laurent Maron, Grégory Nocton
Format: Article
Language:English
Published: MDPI AG 2018-08-01
Series:Inorganics
Subjects:
Online Access:http://www.mdpi.com/2304-6740/6/3/82