Total Structure, Structural Transformation and Catalytic Hydrogenation of [Cu41(SC6H3F2)15Cl3(P(PhF)3)6(H)25]2− Constructed from Twisted Cu13 Units

Total Structure, Structural Transformation and Catalytic Hydrogenation of [Cu41(SC6H3F2)15Cl3(P(PhF)3)6(H)25]2− Constructed from Twisted Cu13 Units

Abstract Herein, a remarkable achievement in the synthesis and characterization of an atomically precise copper‐hydride nanocluster, [Cu41(SC6H3F2)15Cl3(P(PhF)3)6(H)25]2− via a mild one‐pot reaction is presented. Through X‐ray crystallography analysis, it is revealed that [Cu41(SC6H3F2)15Cl3(P(PhF)3...

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Bibliographic Details
Main Authors: Huimin Zhou, Tengfei Duan, Zidong Lin, Tao Yang, Huijuan Deng, Shan Jin, Yong Pei, Manzhou Zhu
Format: Article
Language:English
Published: Wiley 2024-02-01
Series:Advanced Science
Subjects:
copper nanocluster
electronic structure
high hydrogenation activity
the nanocluster‐to‐nanocluster transformation
twisted Cu13 units assemble
Online Access:https://doi.org/10.1002/advs.202307085

Internet

https://doi.org/10.1002/advs.202307085

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