A New Nanometer-Sized Ga(III)-Oxyhydroxide Cation

A New Nanometer-Sized Ga(III)-Oxyhydroxide Cation

A new 30-center Ga(III)-oxy-hydroxide cation cluster was synthesized by hydrolysis of an aqueous GaCl3 solution near pH = 2.5 and crystallized using 2,6-napthalene disulfonate (NDS). The cluster has 30 metal centers and a nominal stoichiometry: [Ga30(μ4-O)12(μ3-O)4(μ3-OH)4(μ2-OH)42(H2O)16](2,6-NDS)...

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Bibliographic Details
Main Authors: William H. Casey, Marilyn M. Olmstead, Caitlyn R. Hazlett, Chelsey Lamar, Tori Z. Forbes
Format: Article
Language:English
Published: MDPI AG 2015-02-01
Series:Inorganics
Subjects:
gallium hydroxide
polyxocation
Keggin ion
Group 13 cations
Online Access:http://www.mdpi.com/2304-6740/3/1/21

Internet

http://www.mdpi.com/2304-6740/3/1/21

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