Enhancement of InN Luminescence by Introduction of Graphene Interlayer

Indium nitride (InN) luminescence is substantially enhanced by the introduction of a multilayer graphene interlayer, mitigating the lattice mismatch between the InN epilayer and the Gallium nitride (GaN) template on a sapphire substrate via weak van der Waals interaction between graphene and nitride...

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Main Authors: Darius Dobrovolskas, Shingo Arakawa, Shinichiro Mouri, Tsutomu Araki, Yasushi Nanishi, Jūras Mickevičius, Gintautas Tamulaitis
Format: Article
Language:English
Published: MDPI AG 2019-03-01
Series:Nanomaterials
Subjects:
Online Access:http://www.mdpi.com/2079-4991/9/3/417
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author Darius Dobrovolskas
Shingo Arakawa
Shinichiro Mouri
Tsutomu Araki
Yasushi Nanishi
Jūras Mickevičius
Gintautas Tamulaitis
author_facet Darius Dobrovolskas
Shingo Arakawa
Shinichiro Mouri
Tsutomu Araki
Yasushi Nanishi
Jūras Mickevičius
Gintautas Tamulaitis
author_sort Darius Dobrovolskas
collection DOAJ
description Indium nitride (InN) luminescence is substantially enhanced by the introduction of a multilayer graphene interlayer, mitigating the lattice mismatch between the InN epilayer and the Gallium nitride (GaN) template on a sapphire substrate via weak van der Waals interaction between graphene and nitride layers. The InN epilayers are deposited by radio-frequency plasma-assisted molecular beam epitaxy (MBE), and are characterized by spatially-resolved photoluminescence spectroscopy using confocal microscopy. A small blue shift of the emission band from the band gap evidences a low density of equilibrium carriers, and a high quality of InN on multilayer graphene. A deposition temperature of ~375 °C is determined as optimal. The granularity, which is observed for the InN epilayers deposited on multilayer graphene, is shown to be eliminated, and the emission intensity is further enhanced by the introduction of an aluminum nitride (AlN) buffer layer between graphene and InN.
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spelling doaj.art-8a01ee7a9ed64dfc86bc3b6b15f118a62022-12-21T19:49:39ZengMDPI AGNanomaterials2079-49912019-03-019341710.3390/nano9030417nano9030417Enhancement of InN Luminescence by Introduction of Graphene InterlayerDarius Dobrovolskas0Shingo Arakawa1Shinichiro Mouri2Tsutomu Araki3Yasushi Nanishi4Jūras Mickevičius5Gintautas Tamulaitis6Institute of Photonics and Nanotechnology, Vilnius University, Sauletekio al. 3, LT-10257 Vilnius, LithuaniaDepartment of Electrical and Electronic Engineering, Ritsumeikan University, Kusatsu, Shiga 525-8577, JapanDepartment of Electrical and Electronic Engineering, Ritsumeikan University, Kusatsu, Shiga 525-8577, JapanDepartment of Electrical and Electronic Engineering, Ritsumeikan University, Kusatsu, Shiga 525-8577, JapanDepartment of Electrical and Electronic Engineering, Ritsumeikan University, Kusatsu, Shiga 525-8577, JapanInstitute of Photonics and Nanotechnology, Vilnius University, Sauletekio al. 3, LT-10257 Vilnius, LithuaniaInstitute of Photonics and Nanotechnology, Vilnius University, Sauletekio al. 3, LT-10257 Vilnius, LithuaniaIndium nitride (InN) luminescence is substantially enhanced by the introduction of a multilayer graphene interlayer, mitigating the lattice mismatch between the InN epilayer and the Gallium nitride (GaN) template on a sapphire substrate via weak van der Waals interaction between graphene and nitride layers. The InN epilayers are deposited by radio-frequency plasma-assisted molecular beam epitaxy (MBE), and are characterized by spatially-resolved photoluminescence spectroscopy using confocal microscopy. A small blue shift of the emission band from the band gap evidences a low density of equilibrium carriers, and a high quality of InN on multilayer graphene. A deposition temperature of ~375 °C is determined as optimal. The granularity, which is observed for the InN epilayers deposited on multilayer graphene, is shown to be eliminated, and the emission intensity is further enhanced by the introduction of an aluminum nitride (AlN) buffer layer between graphene and InN.http://www.mdpi.com/2079-4991/9/3/417grapheneindium nitridemolecular beam epitaxyphotoluminescence
spellingShingle Darius Dobrovolskas
Shingo Arakawa
Shinichiro Mouri
Tsutomu Araki
Yasushi Nanishi
Jūras Mickevičius
Gintautas Tamulaitis
Enhancement of InN Luminescence by Introduction of Graphene Interlayer
Nanomaterials
graphene
indium nitride
molecular beam epitaxy
photoluminescence
title Enhancement of InN Luminescence by Introduction of Graphene Interlayer
title_full Enhancement of InN Luminescence by Introduction of Graphene Interlayer
title_fullStr Enhancement of InN Luminescence by Introduction of Graphene Interlayer
title_full_unstemmed Enhancement of InN Luminescence by Introduction of Graphene Interlayer
title_short Enhancement of InN Luminescence by Introduction of Graphene Interlayer
title_sort enhancement of inn luminescence by introduction of graphene interlayer
topic graphene
indium nitride
molecular beam epitaxy
photoluminescence
url http://www.mdpi.com/2079-4991/9/3/417
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AT tsutomuaraki enhancementofinnluminescencebyintroductionofgrapheneinterlayer
AT yasushinanishi enhancementofinnluminescencebyintroductionofgrapheneinterlayer
AT jurasmickevicius enhancementofinnluminescencebyintroductionofgrapheneinterlayer
AT gintautastamulaitis enhancementofinnluminescencebyintroductionofgrapheneinterlayer