Mechanochemistry Drives Alkene Difunctionalization via Radical Ligand Transfer and Electron Catalysis

Mechanochemistry Drives Alkene Difunctionalization via Radical Ligand Transfer and Electron Catalysis

Abstract A general and modular protocol is reported for olefin difunctionalization through mechanochemistry, facilitated by cooperative radical ligand transfer (RLT) and electron catalysis. Utilizing mechanochemical force and catalytic amounts of 2,2,6,6‐tetramethylpiperidinyloxyl (TEMPO), ferric ni...

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Bibliographic Details
Main Authors: Subrata Patra, Bhargav N. Nandasana, Vasiliki Valsamidou, Dmitry Katayev
Format: Article
Language:English
Published: Wiley 2024-08-01
Series:Advanced Science
Subjects:
electron catalysis
mechanochemistry
nitration
olefin difunctionalization
radical ligand transfer (RLT)
Online Access:https://doi.org/10.1002/advs.202402970

Internet

https://doi.org/10.1002/advs.202402970

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