Silicon-oriented regio- and enantioselective rhodium-catalyzed hydroformylation
Hydroformylation of 1,2-disubstituted alkenes usually occurs at the α position of the directing heteroatom. Here, the authors report the asymmetric rhodium-catalyzed hydroformylation of 1,2-disubstituted alkenylsilanes with excellent regioselectivity at the β position (relative to the silicon hetero...
Главные авторы: | , , , , , , , , , |
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Формат: | Статья |
Язык: | English |
Опубликовано: |
Nature Portfolio
2018-05-01
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Серии: | Nature Communications |
Online-ссылка: | https://doi.org/10.1038/s41467-018-04277-7 |