Silicon-oriented regio- and enantioselective rhodium-catalyzed hydroformylation

Hydroformylation of 1,2-disubstituted alkenes usually occurs at the α position of the directing heteroatom. Here, the authors report the asymmetric rhodium-catalyzed hydroformylation of 1,2-disubstituted alkenylsilanes with excellent regioselectivity at the β position (relative to the silicon hetero...

Полное описание

Библиографические подробности
Главные авторы: Cai You, Xiuxiu Li, Yuhong Yang, Yu-Sheng Yang, Xuefeng Tan, Shuailong Li, Biao Wei, Hui Lv, Lung-Wa Chung, Xumu Zhang
Формат: Статья
Язык:English
Опубликовано: Nature Portfolio 2018-05-01
Серии:Nature Communications
Online-ссылка:https://doi.org/10.1038/s41467-018-04277-7