Cobalt-catalyzed nucleophilic addition of the allylic C(sp3)–H bond of simple alkenes to ketones
We herein describe a cobalt/Xantphos-catalyzed regioselective addition of simple alkenes to acetophenone derivatives, affording branched homoallylic alcohols in high yields with perfect branch selectivities. The intermediate of the reaction would be a nucleophilic allylcobalt(I) species generated vi...
| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | English |
| Publicado em: |
Beilstein-Institut
2018-08-01
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| Colecção: | Beilstein Journal of Organic Chemistry |
| Assuntos: | |
| Acesso em linha: | https://doi.org/10.3762/bjoc.14.176 |