Enantioselective 1,3-Dipolar Cycloaddition Using (<i>Z</i>)-α-Amidonitroalkenes as a Key Step to the Access to Chiral <i>cis</i>-3,4-Diaminopyrrolidines

Enantioselective 1,3-Dipolar Cycloaddition Using (<i>Z</i>)-α-Amidonitroalkenes as a Key Step to the Access to Chiral <i>cis</i>-3,4-Diaminopyrrolidines

The enantioselective 1,3-dipolar cycloaddition between imino esters and (<i>Z</i>)-nitroalkenes bearing a masked amino group in the β-position was studied using several chiral ligands and silver salts. The optimized reaction conditions were directly applied to the study of the scope of t...

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Bibliographic Details
Main Authors: Eduardo García-Mingüens, Marcos Ferrándiz-Saperas, M. de Gracia Retamosa, Carmen Nájera, Miguel Yus, José M. Sansano
Format: Article
Language:English
Published: MDPI AG 2022-07-01
Series:Molecules
Subjects:
nitroprolinates
enantioseletive cycloaddition
phosphoramidite
azomethine ylides
diamines
Online Access:https://www.mdpi.com/1420-3049/27/14/4579

Internet

https://www.mdpi.com/1420-3049/27/14/4579

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