Synthesis and X-ray crystal structures of heteroleptic zinc amidinate complexes

Synthesis and X-ray crystal structures of heteroleptic zinc amidinate complexes

The synthesis of heteroleptic zinc amidinate complexes is reported. Reactions of LZnI [L=t-BuC(NDipp)2; Dipp=2,6-i-Pr2-C6H3] with diisopropylcarbodiimide (i-PrN)2C yielded the Lewis acid-base adduct LZn(I)-N(i-Pr)CN(i-Pr) 1. In addition, the synthesis of LZnN(SiMe3)22 and its reaction with (i-PrN)2C...

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Bibliographic Details
Main Authors: Schmidt Sarah, Schulz Stephan, Bläser Dieter, Wölper Christoph
Format: Article
Language:English
Published: De Gruyter 2012-05-01
Series:Main Group Metal Chemistry
Subjects:
amidinate
crystal structure
zinc
Online Access:https://doi.org/10.1515/mgmc-2012-0004

Internet

https://doi.org/10.1515/mgmc-2012-0004

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