Synthesis and X-ray crystal structures of heteroleptic zinc amidinate complexes
The synthesis of heteroleptic zinc amidinate complexes is reported. Reactions of LZnI [L=t-BuC(NDipp)2; Dipp=2,6-i-Pr2-C6H3] with diisopropylcarbodiimide (i-PrN)2C yielded the Lewis acid-base adduct LZn(I)-N(i-Pr)CN(i-Pr) 1. In addition, the synthesis of LZnN(SiMe3)22 and its reaction with (i-PrN)2C...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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De Gruyter
2012-05-01
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| Series: | Main Group Metal Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.1515/mgmc-2012-0004 |
| _version_ | 1819130356160266240 |
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| author | Schmidt Sarah Schulz Stephan Bläser Dieter Wölper Christoph |
| author_facet | Schmidt Sarah Schulz Stephan Bläser Dieter Wölper Christoph |
| author_sort | Schmidt Sarah |
| collection | DOAJ |
| description | The synthesis of heteroleptic zinc amidinate complexes is reported. Reactions of LZnI [L=t-BuC(NDipp)2; Dipp=2,6-i-Pr2-C6H3] with diisopropylcarbodiimide (i-PrN)2C yielded the Lewis acid-base adduct LZn(I)-N(i-Pr)CN(i-Pr) 1. In addition, the synthesis of LZnN(SiMe3)22 and its reaction with (i-PrN)2C, which occurred with formation of the heteroleptic amidinate-guanidinate complex LZnL′ 3 [L′=(Me3Si)2NC(Ni-Pr)2], is reported. Compounds 1–3 were characterized by nuclear magnetic resonance (1H, 13C) and infrared spectro\xadscopy, elemental analysis, and single crystal X-ray diffraction (1 and 2), respectively. |
| first_indexed | 2024-12-22T08:58:18Z |
| format | Article |
| id | doaj.art-8afd0d15fbe2449db89789d905656497 |
| institution | Directory Open Access Journal |
| issn | 0792-1241 2191-0219 |
| language | English |
| last_indexed | 2024-12-22T08:58:18Z |
| publishDate | 2012-05-01 |
| publisher | De Gruyter |
| record_format | Article |
| series | Main Group Metal Chemistry |
| spelling | doaj.art-8afd0d15fbe2449db89789d9056564972022-12-21T18:31:47ZengDe GruyterMain Group Metal Chemistry0792-12412191-02192012-05-01351-2354010.1515/mgmc-2012-0004Synthesis and X-ray crystal structures of heteroleptic zinc amidinate complexesSchmidt Sarah0Schulz Stephan1Bläser Dieter2Wölper Christoph3Institute of Inorganic Chemistry, University of Duisburg-Essen, D-45117 Essen, GermanyInstitute of Inorganic Chemistry, University of Duisburg-Essen, D-45117 Essen, GermanyInstitute of Inorganic Chemistry, University of Duisburg-Essen, D-45117 Essen, GermanyInstitute of Inorganic Chemistry, University of Duisburg-Essen, D-45117 Essen, GermanyThe synthesis of heteroleptic zinc amidinate complexes is reported. Reactions of LZnI [L=t-BuC(NDipp)2; Dipp=2,6-i-Pr2-C6H3] with diisopropylcarbodiimide (i-PrN)2C yielded the Lewis acid-base adduct LZn(I)-N(i-Pr)CN(i-Pr) 1. In addition, the synthesis of LZnN(SiMe3)22 and its reaction with (i-PrN)2C, which occurred with formation of the heteroleptic amidinate-guanidinate complex LZnL′ 3 [L′=(Me3Si)2NC(Ni-Pr)2], is reported. Compounds 1–3 were characterized by nuclear magnetic resonance (1H, 13C) and infrared spectro\xadscopy, elemental analysis, and single crystal X-ray diffraction (1 and 2), respectively.https://doi.org/10.1515/mgmc-2012-0004amidinatecrystal structurezinc |
| spellingShingle | Schmidt Sarah Schulz Stephan Bläser Dieter Wölper Christoph Synthesis and X-ray crystal structures of heteroleptic zinc amidinate complexes Main Group Metal Chemistry amidinate crystal structure zinc |
| title | Synthesis and X-ray crystal structures of heteroleptic zinc amidinate complexes |
| title_full | Synthesis and X-ray crystal structures of heteroleptic zinc amidinate complexes |
| title_fullStr | Synthesis and X-ray crystal structures of heteroleptic zinc amidinate complexes |
| title_full_unstemmed | Synthesis and X-ray crystal structures of heteroleptic zinc amidinate complexes |
| title_short | Synthesis and X-ray crystal structures of heteroleptic zinc amidinate complexes |
| title_sort | synthesis and x ray crystal structures of heteroleptic zinc amidinate complexes |
| topic | amidinate crystal structure zinc |
| url | https://doi.org/10.1515/mgmc-2012-0004 |
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