Controlled oligomerization of [1.1.1]propellane through radical polarity matching: selective synthesis of SF5- and CF3SF4-containing [2]staffanes

Controlled oligomerization of [1.1.1]propellane through radical polarity matching: selective synthesis of SF5- and CF3SF4-containing [2]staffanes

Selectivity in radical chain oligomerizations involving [1.1.1]propellane – i.e., to make [n]staffanes – has been notoriously challenging to control when n > 1 is desired. Herein, we report selective syntheses of SF5- and CF3SF4-containing [2]staffanes from SF5Cl and CF3SF4Cl, demonstrating cases...

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Bibliographic Details
Main Authors: Jón Atiba Buldt, Wang-Yeuk Kong, Yannick Kraemer, Masiel M. Belsuzarri, Ansh Hiten Patel, James C. Fettinger, Dean J. Tantillo, Cody Ross Pitts
Format: Article
Language:English
Published: Beilstein-Institut 2024-11-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
pentafluorosulfanylation
[1.1.1]propellane
radical chain oligomerization
staffanes
strain-release
Online Access:https://doi.org/10.3762/bjoc.20.259

Internet

https://doi.org/10.3762/bjoc.20.259

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