Effective screening of Coulomb repulsions in water accelerates reactions of like-charged compounds by orders of magnitude

The reaction speed of like-charged compounds in water is extremely slow due to Coulomb repulsions. Here, the authors boost kinetics up to 5 million times by screening these interactions and increasing the local concentration of reactants using positively charged micelles. They show the effect for tw...

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Bibliographic Details
Main Authors: Adam Kowalski, Krzysztof Bielec, Grzegorz Bubak, Pawel J. Żuk, Maciej Czajkowski, Volodymyr Sashuk, Wilhelm T. S. Huck, Jan M. Antosiewicz, Robert Holyst
Format: Article
Language:English
Published: Nature Portfolio 2022-10-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-022-34182-z